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Germyl anions transition metal halides

Synthesis from transition metal halides and germyl anions. 1245... [Pg.1241]

Synthesis from transition metal anions and germyl halides. 1244... [Pg.1241]

Germyl metallocene derivatives of the early transition metals, Ti, Zr and Hf (M) have been synthesized by the combination of metallocene halides and germyl anions (equations 4 and 5)38-40. The cyclopentadienyl complexes Cp2M(GePh3)Cl39 are difficult to purify due to their instability in solution however, use of the pentamethylcyclopen-tadienyl group(Cp ) enhances both the solubility and stability of these complexes40,41. [Pg.1245]

The asymmetric germyl anion also permitted preparation of chiral germyl-transition-metal complexes (35, 36) by substitution of a halogen from a metal halide (eq. [15]). [Pg.52]

See other pages where Germyl anions transition metal halides is mentioned: [Pg.450]    [Pg.157]    [Pg.174]   
See also in sourсe #XX -- [ Pg.4 , Pg.5 , Pg.8 ]



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Anions germyl

Germyl

Germyl halides

Germyls

Halides transition-metal

Metal anionic

Metal anions

Metal germyls

Transition metal anions

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