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Genipic acid

With a similar sequence it has been established that the assumed structural formula for genipic acid is not the correct one 475), as the cyclopentene derivative in (4.64) does not behave like the natural product itself. [Pg.62]

Related synthetic work concerns the preparation of 2-isopropyl-5-methyl-cyclopentanone, syntheses of a number of chiral cyclopentanoid aldehydes and ketones and (113) (c/. Vol. 8, p. 38), and a number of unsuccessful attempts to synthesize genipic acid. ... [Pg.46]

From the fruit of the Puerto Rican plant Genipa americana L.y Tallent (1964) isolated the cyclopentanoid antibiotic genipic acid, C9H12O4. From its spectral properties and reactions [especially a chemical correlation with aucubin (VIII)], he deduced the structure I for it, except for the absolute configuration, which has only recently been established for aucubin (VIII) and therefore genipic acid (I). [Pg.137]

This antibiotic certainly has a close biogenetic relationship to genipic acid, and a possible pathway to these substances was given on p. I37. [Pg.138]

See other pages where Genipic acid is mentioned: [Pg.640]    [Pg.430]    [Pg.640]    [Pg.640]    [Pg.60]    [Pg.640]    [Pg.197]    [Pg.43]    [Pg.91]    [Pg.252]    [Pg.305]    [Pg.137]    [Pg.137]    [Pg.138]    [Pg.138]    [Pg.162]    [Pg.190]    [Pg.640]    [Pg.430]    [Pg.640]    [Pg.640]    [Pg.60]    [Pg.640]    [Pg.197]    [Pg.43]    [Pg.91]    [Pg.252]    [Pg.305]    [Pg.137]    [Pg.137]    [Pg.138]    [Pg.138]    [Pg.162]    [Pg.190]    [Pg.430]   
See also in sourсe #XX -- [ Pg.15 ]

See also in sourсe #XX -- [ Pg.43 ]

See also in sourсe #XX -- [ Pg.137 ]



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