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Gel Impregnated Resins

High polymers swell and form gels when they are soaked in solubility-consistent organic solvents. Cross-linkage can limit the swelling and prevent the polymer from being entirely dissolved in the solvent. If the organic [Pg.277]

Applications of Liquid Gel Impregnated Resins in Metal Extraction Processes [Pg.278]

Despite extensive studies and applications of liquid-liquid extraction, only a few papers have appeared that deal with the extraction of metals by liquid-hydrophobic gels. Typical examples are the extraction of U(Vl), Th(IV), [Pg.278]

Ce(III), and Co(II) with styrene-divinylbenzene swollen with di-(2-ethyl-hexyOphosphoric acid [189-191], and only a few papers, mainly for analytical purposes, are available [188,192]. [Pg.279]

Extracting hydrophobic gels prepared by swelling cross-linked polybutadiene with solutions of 4-acylpyrazol-5-one (HL) in toluene, chloroform, and carbon tetrachloride were used for copper extraction studies [192]. The metal distribution curves, close to those obtained in the pure liquid-liquid extraction systems, show that the polymer has no effect on the thermodynamics of the liquid-gel extraction, as shown in Fig. 43. Kinetic studies [Pg.279]


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