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Gas-Solid Isothermal and Thermochromatography

Based on a microscopic model of gas-solid thermochromatography in open columns by Zvara (1985), a Monte Carlo code has been made available (Tiirler 1996), which allows to generate thermochromatographic deposition zones as well as yield versus temperature curves as observed in isothermal chromatography. This model accommodates the influence of the carrier gas flow, the actual temperature profiles, and the different half-lives of the investigated species. For each isothermal temperature, the transport through the column is modeled for a large number of sample molecules. These calculations result in a curve of yield versus temperature for each value of the adsorption enthalpy The curve for the particular... [Pg.936]


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Gas thermochromatography

Gases and Solids

Gas—Isothermal

Thermochromatography

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