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Gallium-silicon cluster

Clusters of the elements aluminum to thallium containing only one or two carbon atoms and strong direct element-element interactions, similar to boron rich car-baboranes, have not yet been synthesized, and also the corresponding silicon derivatives are relatively rare. To the best of our knowledge only one aluminum-silicon and one gallium-silicon cluster (1 and 2) has been reported in the literature. The reaction of metastable aluminum(I) chloride with decamethylsilicocene or with a mixture of SiCl4 and (AlCp )4, respectively, afforded black crystals of... [Pg.357]

Keywords Gallium-Silicon Heterocycles / Hypersilyl / Main Group Elements / Clusters... [Pg.207]

See other pages where Gallium-silicon cluster is mentioned: [Pg.358]    [Pg.128]    [Pg.724]    [Pg.728]    [Pg.357]    [Pg.352]    [Pg.1379]    [Pg.1402]    [Pg.183]    [Pg.437]    [Pg.635]    [Pg.1378]    [Pg.1401]    [Pg.324]    [Pg.244]    [Pg.724]    [Pg.725]    [Pg.747]    [Pg.301]   
See also in sourсe #XX -- [ Pg.357 ]



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