Gallium-nitrogen compounds

Gallium Nitrogen Compounds. Direct combination of gaUium and nitrogen (40) involves a gas discharge at 750°C for the dissociation of... 

Examples of Ga derivatives with double bond character to group 15 centers have attracted much attention and reviewd " Power and coworkers recently published compounds with gallium-nitrogen multiple bondsd and the first example of a Ga=As derivative, [ Li(THF)3 2Ga2 As(SiPr3) 4], has recently been synthesized and contains two As=Ga double bonds from the reaction of Gads with Li2AsSiPr ... 

These compoimds, and their gallium and indium analogs, serve as precursors for Group 13 nitride materials (AIN, GaN, InN) [117]. Because aluminum-nitrogen compounds have been reviewed [118-121], selected recent examples only will be discussed here. It is worth mentioning that recent mass spectral measurements show that the dimeric aggregates are preserved even in the gas phase, with partial disso-... 

This chapter emphasizes cage and cluster compounds of aluminum, gallium and indium incorporating nitrogen atoms. A search of the literature reveals a number of monographs and reviews [31-33] as well as recent research articles available on this subject. Reactions of alanes and alanates with various amines leading to iminoalanes and aminoalanes have been well documented [21, 31, 34-36], In summary, there are reports on the formation of iminoalanes from Eqs. (13) to (17). 

---