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Gallium alkyls

Furthermore, gallium compounds can serve as model systems for aluminum congeners. Cationic gallium alkyls are of interest in synthesis and catalytic applications involving polar substituents because of the relative stability of the Ga—R bond toward hydrolysis and electrophilic cleavage compared to the otherwise superior Al-R species [11]. [Pg.87]

Other high molecular weight amines to have been successfully used for adduct purification include the aza-crown macrocycles Me4-14-ane-N4 and Me6-18-ane-N6.48 These reversibly form adducts with indium and gallium alkyls, such as [(Et3Ga)4(Me6-18-ane-N6)], [(Et3Ga)6(Me6-18-ane-N6)], [(Pr13Ga)4(Me6-18-ane-N6)], and [(Pr13Ga)4(Me4-14-ane-N4)].49 Formation of... [Pg.1019]

The coordination of pnictogen ligands to gallium alkyl compounds has also been used in purification techniques similar to those implemented for its indium analogs see Indium Organometallic Chemistry). For example, [RyGa L] where... [Pg.1382]

See other pages where Gallium alkyls is mentioned: [Pg.107]    [Pg.108]    [Pg.336]    [Pg.2]    [Pg.118]    [Pg.119]    [Pg.306]    [Pg.310]    [Pg.119]    [Pg.1371]    [Pg.1379]    [Pg.1397]    [Pg.1397]    [Pg.1398]    [Pg.387]    [Pg.95]    [Pg.249]    [Pg.1370]    [Pg.1378]    [Pg.1396]    [Pg.1396]    [Pg.1397]    [Pg.466]    [Pg.59]   
See also in sourсe #XX -- [ Pg.77 , Pg.84 , Pg.89 , Pg.90 , Pg.93 , Pg.95 ]

See also in sourсe #XX -- [ Pg.99 ]



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