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2-Furfuryl alcohol Claisen-Cope rearrangement

Thomas and Ozainne" have explored the tandem Claisen-Cope rearrangement on aromatic substrates. Treatment of 2-furfuryl alcohol with diene (25 equation 9) provides a 9 1 mixture of Claisen-Cope product (39) and furan (37), respectively. The minor component arises via the forbidden [1,3] prototropic shift of the initial Claisen intermediate (38), thereby reestablishing the aromaticity of the furan ring. [Pg.879]


See other pages where 2-Furfuryl alcohol Claisen-Cope rearrangement is mentioned: [Pg.879]    [Pg.879]   
See also in sourсe #XX -- [ Pg.879 ]

See also in sourсe #XX -- [ Pg.5 ]

See also in sourсe #XX -- [ Pg.5 ]




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Claisen-Cope rearrangement

Furfuryl alcohol

Furfurylic alcohol

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