Fundamental Rules FI and

How the fundamental rules FI and F2 lead to the experimentally observed promotional rules LI, L2 and G1 to G4. 

As shown recently11 these two fundamental rules lead directly mathematically to the experimental mles LI and L2 (Eqs. 6.11, 6.12 and, for low coverages, to mle G4, eq. 6.13). Henceforth the global mles G1 to G4 are all derived on the basis of the fundamental mles FI and F2. 

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Derivation of the experimental local rules LI and L2 from the fundamental rules FI and F2... 

The concepts of classical and quantum physics allow one, either exactly or with a certain probability, to predict the state of macrobodies or microparticles. In particular, this concerns mechanical movement regularities, which can be described by using spatial-temporal, coordinates, the vales of mass, velocity, pulse, wave characteristics, the knowledge of the fundamental t5q)e of interaction. However, there exist some processes whose features can be explained by neither classical physics nor quantum representations. E.g. the existence of bodies to them in different aggregation states, the appearance of elastic forces at deformations of systems, possible transformation of some compounds into others, etc. As a rule, these and similar processes are accompanied by transition of systems fi om one state to another one with changes in thermal energy. Just such processes and most general thermal properties of macroscopic bodies are studied by the section of physics and chemistry called thermodynamics [1, 2, 9-11]. 

The fundamental physico-chemical characteristics which enter into the evaluation of these component forces are the dipole moments, fi, the ionization potentials, /, and the polarizabilities, a, of the base pairs. The polarizabilities may be obtained relatively easily by the use of the usual additivity rules . The problems of the ionization potentials and of the dipole moments are however much more difficult. As concerns the ionization potentials they are completely unknown experimentally for the biological purines and pyrimidines (as they are, in fact, for the great majority of biomolecules). As concerns the dipole moments only those of some simple derivatives of purine, adenine and uracil are known no information exists about the moments of guanine or cytosine. 

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