Fundamental equations atmospheric diffusion equation

Deterministic air quaUty models describe in a fundamental manner the individual processes that affect the evolution of pollutant concentrations. These models are based on solving the atmospheric diffusion —reaction equation, which is in essence the conservation-of-mass principle for each pollutant species... 

The sections of this chapter deal with the following elements of atmospheric dynamics vertical structure of the atmosphere (Section 3.2), fundamental equations of atmospheric motions (Section 3.3), transport of chemical constituents and the relative importance of dynamical and chemical effects on photochemical species (Section 3.4), atmospheric waves (Section 3.5), the mean meridional circulation and the use of the transformed Eulerian formalism to illustrate the roles of mean meridional and eddy transports (Section 3.6), the important role of wave transience and dissipation (Section 3.7), vertical transport by molecular diffusion in the thermosphere (Section 3.8), and finally, models of the middle atmosphere (Section 3.9). 

Interpretation of available data is frustrated by lack of knowledge of certain fundamental quantities such as Interfacial area, mass transfer coefficients, solubility data, diffusion coefficients, bubble sizes, etc.. Existing equations for almost all of these variables have been developed on the basis of experiments conducted at atmospheric pressure and around room temperature. Use of such predictive equations at the reacting conditions involves large extrapolation, and the combined errors would make the analysis of kinetic data very suspect. In spite of this, most work reported in the literature does use such correlations. 

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