From kinetic measurements macroscopic description

Determination of Bond Dissociation Energies from Kinetic Measurements Macroscopic Description... 

The link between the microscopic description of the reaction dynamics and the macroscopic kinetics that can be measured in a catalytic reactor is a micro-kinetic model. Such a model will start from binding energies and reaction rate constants deduced from surface science experiments on well defined single crystal surfaces and relate this to the macroscopic kinetics of the reaction. 

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