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From haloethanes

To see qualitatively why the vibrationally adiabatic picture breaks down, consider HX elimination from haloethane, H3C—CH2X H2C=CH2 + HX. Here... [Pg.65]

Rao, Velliyur Nott Malhkaijun Rosenfeld, H. David Subramoney, Shekhar Subra-manian, Munirpallam A. Sievert, Allen C. Fluorination process and catalyst for the preparation of 1,1,1,2,2-pentafluoroethane from haloethanes and/or haloethylenes and hydrogen fluoride. WO 2004018396Al-20040304 (2004). [Pg.433]

Glyoxal has been obtained by several methods, only a few of which are of preparative value. The most feasible are the oxidation of acetaldehyde by nitric3 4 5 or selenious6 acid the hydrolysis of dichlorodioxane 7 and the hydrolysis of the product resulting from the action of fuming sulfuric acid upon tetra-haloethanes.8... [Pg.33]

To probe the effects of HCFC structure on toxicity the metabolism of three penta-haloethanes, HCFC-123, HCFC-124, and HCFC-125 were studied. The three compounds differ one from the other by the number of fluorine atoms present in the /3-carbon (Fig. 4.64). It was found that the enthalpies of activation, AHact, for hydrogen atom abstraction paralleled the rate of trifluoroacetic acid excretion suggesting that the more difficult it was... [Pg.84]

Summary of AE s Obtained in Several Ways for Some Liquid Haloethanes which have Two Equivalent gauche Forms (From Gutowsky, Belford and McMahon, 1962)... [Pg.251]


See other pages where From haloethanes is mentioned: [Pg.128]    [Pg.131]    [Pg.131]    [Pg.68]    [Pg.1573]    [Pg.131]    [Pg.65]    [Pg.238]    [Pg.170]    [Pg.312]   
See also in sourсe #XX -- [ Pg.254 ]




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Haloethanes

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