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Formation of One Bond Adjacent to a Heteroatom

Sulfamate indan-2-yl ester 145 is oxidized by iodobenzene diacetate to give condensed 1,2,3-oxathiazole di-A-oxides 146 (Equation 35). Various rhodium 2001JA6935, 2004HCA1607 , manganese(m) Schiff base 2005TL5403 , and ruthenium porphyrin 2002AGE3465 catalysts can be used for this transformation. Enantioselective intramolecular amidation is achieved with good yields. [Pg.25]

Monocyclic optically active cyclic sulfamidates 147 can also be obtained by this method 2005TL5403 . [Pg.25]

See other pages where Formation of One Bond Adjacent to a Heteroatom is mentioned: [Pg.199]    [Pg.200]    [Pg.200]    [Pg.215]    [Pg.242]    [Pg.254]    [Pg.409]    [Pg.425]    [Pg.433]    [Pg.448]    [Pg.453]    [Pg.477]    [Pg.492]    [Pg.527]    [Pg.199]    [Pg.200]    [Pg.200]    [Pg.215]    [Pg.242]    [Pg.254]    [Pg.25]    [Pg.37]    [Pg.51]    [Pg.61]    [Pg.88]    [Pg.106]    [Pg.127]    [Pg.898]    [Pg.931]    [Pg.199]    [Pg.200]    [Pg.200]    [Pg.215]    [Pg.242]    [Pg.254]    [Pg.898]    [Pg.931]    [Pg.668]    [Pg.669]    [Pg.670]    [Pg.670]    [Pg.671]    [Pg.672]    [Pg.674]    [Pg.675]    [Pg.677]   


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Adjacency

Adjacent

Bonds heteroatom

Formation of a,-bonds

Formation of bonds

Heteroatom Bond Formation

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