Formation constants of metal complexes

In Section 8, the material on solubility constants has been doubled to 550 entries. Sections on proton transfer reactions, including some at various temperatures, formation constants of metal complexes with organic and inorganic ligands, buffer solutions of all types, reference electrodes, indicators, and electrode potentials are retained with some revisions. The material on conductances has been revised and expanded, particularly in the table on limiting equivalent ionic conductances. 

Formation constants of metal complexes in non-aqueous solvents, part III DMSO. R. C, Kapoor,... 

Many potentiometric studies have been carried out to obtain information about the compositions and formation constants of metal complexes in non-aqueous solutions. Ion-selective electrodes and metal (or metal amalgam) electrodes are used as indicator electrodes. 

Figure 6-6 Logarithms of formation constants of metal complexes of histidine, glycine, and ATP plotted against the atomic number of elements from manganese to zinc.

Table 8 Formation Constants of Metal Complexes of EDTA3...

One of the methods by which the formation constants of metal complexes can be determined involves the measurement of electrode potentials of half cells of the type M" + ne M in a series of solution of varying ligand concentrations. 

Table 1. Logarithms of the formation constants of metal complexes of Me3[21]aneN502, Me3[24]aneN5p3 and [21]aneN502, determined by means of potentiometric measurements in 0.15 mol dm NaC104 aqueous solution at 298.15 K (values in parentheses are standard deviations on the last significant figure). ...

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