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Cyclopentadienyl complexes fluxionality

The types of compounds formed by gold(I) and gold(III) often differ from those of other metals due to the constraints imposed by coordination number and electron count at the metal. Thus, for example, whereas 7r-bonded cyclopentadienyl complexes of palladium and platinum are numerous (336), and a copper(I) species of this type is known (337), cyclopentadienyl complexes of univalent (94, 96, 97) and trivalent (228) gold have invariably been found to be fluxional behavior, similar to that in dicyclopentadienylmercury, was involved (228). [Pg.103]

Fluxional and Nonrigid Behavior of Transition Metal Organometallic ir-Complexes, 16, 211 Free Radicals in Organometallic Chemistry, 14, 345 Functionally Substituted Cyclopentadienyl Metal Compounds, 21,1... [Pg.323]


See other pages where Cyclopentadienyl complexes fluxionality is mentioned: [Pg.80]    [Pg.176]    [Pg.34]    [Pg.239]    [Pg.34]    [Pg.239]    [Pg.211]    [Pg.199]    [Pg.467]    [Pg.100]    [Pg.133]    [Pg.252]    [Pg.7]    [Pg.897]    [Pg.76]    [Pg.247]    [Pg.2130]    [Pg.2147]    [Pg.125]    [Pg.250]    [Pg.282]    [Pg.158]    [Pg.242]    [Pg.129]    [Pg.168]    [Pg.1170]    [Pg.2019]    [Pg.4572]    [Pg.208]    [Pg.202]    [Pg.32]    [Pg.897]    [Pg.397]    [Pg.897]    [Pg.179]    [Pg.631]    [Pg.433]    [Pg.22]    [Pg.4571]    [Pg.32]   
See also in sourсe #XX -- [ Pg.578 , Pg.585 , Pg.589 ]

See also in sourсe #XX -- [ Pg.859 , Pg.863 ]




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Complexes cyclopentadienyls

Cyclopentadienyl complex

Cyclopentadienyl complexe

Fluxionality

Fluxions

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