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Fluorophilic ligands

In order to perform fluorous biphasic catalysis the (organometallic) catalyst needs to be solubilized in the fluorous phase by deploying fluorophilic ligands, analogous to the hydrophilic ligands used in aqueous biphasic catalysis. This is accomplished by incorporating so-called fluorous ponytails . [Pg.310]

New phase-separation systems are sought by substituting water for other liquids possessing specific solvent properties reminiscent of those of water. A few include perfluoro-organic liquids (fluorous =fluorme + ( WQ0us catalysis) and supercritical Both require the use of special (fluorophilic) ligands and catalysts having a specific affinity for snch liqnids. [Pg.1291]

See other pages where Fluorophilic ligands is mentioned: [Pg.147]    [Pg.176]    [Pg.1384]    [Pg.1386]    [Pg.1386]    [Pg.63]    [Pg.116]    [Pg.151]    [Pg.154]    [Pg.850]    [Pg.636]    [Pg.23]    [Pg.803]    [Pg.396]    [Pg.469]    [Pg.173]    [Pg.79]    [Pg.921]    [Pg.57]    [Pg.957]    [Pg.69]    [Pg.122]    [Pg.274]   
See also in sourсe #XX -- [ Pg.310 ]



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