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Finding Maxima and Minima

If the second derivative is positive at a point where the first derivative is zero, the point is a minimum if the second derivative is negative, the point is a maximum. If the second derivative is also zero, dyjdx = 0 does not necessarily imply a maximum or a minimum. For instance, the function y = xi has dyjdx = 0 at xq = 0. [Pg.24]


Statement 5. The maximum and minimum problems, providing the maximum and minimum values of the variation of amount of material in the intermediate storage in any failure cycle, are reduced to finding maxima and minima of finite number of functions. [Pg.242]

Most engineering students are well aware that the first derivative of a continuous function is zero at a maximum or minimum of the function. Fewer recall that the sign of the second derivative signifies whether the stationary value determined by a zero first derivative is a maximum or a minimum. Even fewer are aware of what to do if the second derivative happens to be zero. Thus, this appendix is presented to put finding relative maxima and minima of a function on a firm foundation. [Pg.479]

By forming the maxima or minima respectively of these quantities, the extrema being taken over all r with zf 0, we get chirality numbers which are characteristic properties of the skeleton. It should be emphasized that the condition is zfV 0 and not zr 0 because the latter would only lead to trivial numbers which express the fact that a ligand partition is active for any achiral frame if it contains at least one chiral ligand. The nontrivial numbers we want should present information about the pseudoscalar properties of the particular molecular class in question. We find these chirality numbers from the following maxima and minima ... [Pg.67]

To find extrema (maxima and minima) on the isothermals, eq (8) is differentiated with respect to V, keeping T constant ... [Pg.269]

Problem 52 Define the terms maxima and minima and also mention the conditions for finding them. [Pg.33]

Particularly for this maximum-energy structure we find a finer rotational structure around the maximum, which can induce local maxima and minima owing to the hindered rotation of the phosphine s methyl groups. [Pg.89]

In all the radial probability plots, the electron density, or probability of finding the electron, falls off rapidly as the distance from the nucleus increases. It falls olf most quickly for the 1 orbital by r = Sa, the probability is approaching zero. By contrast, the 3d orbital has a maximum at r = 9ao and does not approach zero until approximately r = 20ao- All the orbitals, including the s orbitals, have zero probability at the center of the nucleus, because Anir R = 0 at r = 0. The radial probability ftinctions are a combination of which increases rapidly with r, and R, which may have maxima and minima, but generally decreases exponentially with r. The product of these two factors gives the characteristic probabilities seen in the plots. Because chemical reactions depend on the shape and extent of orbitals at large distances from the nucleus, the radial probability functions help show which orbitals are most likely to be involved in reactions. [Pg.29]

The classical theory of maxima and minima (analytical methods) is concerned with finding the maxima or minima, i.e., extreme points of a function and it provides the theoretical basis for optimization methods and computer programs. This theory determines the values of the n independent variables xi, X2,..., x of a function, where it reaches maxima and minima points. [Pg.2442]

The important matter is the fact that when values of function of two variables are analyzed, the range of material variables (coded values) is narrowed to <-l, 1>. The analysis of graphs (especially in case of hyperbolic paraboloid) shows pairs of maxima and minima (or very clear tendency to the pair of extrema. Considering the mathematics - such result is correct but considering the technical properties - it is necessary to find the extremum that would be correct and rational in an engineering sense. Some of the extrema need to be rejected as they are reached with combinations of material variable values for the polymer-cement coating which are not relevant. Such result was reached in case of the flexibility index in function of coded values polymer to Portland cement ratio (P/C) and hydrophobic agent to Portland cement ratio (H/C). The shape of surface described by this relation was a hyperbolic paraboloid (refer with Fig. 5). [Pg.198]

Despite the lack of quantitative agreement between experiments and theory on the depth and height of the maxima and minima, the angles at which the maxima and minima occur seem to establish the basic diffraction character of the elastic scattering. If one calculates R in Eq. (31-1) from the position of the second and higher minima observed by Strauch for various nuclei, one finds jR = (1.28 0.08) 10 cm. (The position of the first minimum may be... [Pg.491]

What does this free energy per unit volume look like as a function of S and T We could just graph G(S,T) for various values of S and T, but it is more instmctive to do some analysis first. For example, clearly C>0, since a negative value of C would not allow G(S,T) to have a minimum for a finite value of S. In addition, if there is to be a stable nematic phase with a non-zero value of S, then G(S,T) must have a minimum at this value of S. Let us take the derivative of G(S,T) with respect to S and set it equal to zero in order to find the local maxima and minima. [Pg.251]

You can use derivatives to find the extrema of functions (maxima and minima), which predict equilibrium states (as described in Chapters 2 and 3). Maxima or minima in fix) occur at the points w here df/dx = 0. [Pg.64]


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Maxima and minima

Maxima/minima

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