Fert-Butylhydroperoxide

See fert-Butylhydroperoxide Toluene, Dinitrogen pentaoxide See other PEROXYESTERS... 

A recent method reported for the oxidation of primary aliphatic amines to nitro compounds uses fert-butylhydroperoxide (TBHP) and catalytic zirconium tetra-fert-butoxide in presence of molecular sieves. 

Oxidation of Primary Alcohols with fert-Butylhydroperoxide in the Presence of Ruthenium Complexes... 

STRONTIUM NITRATE (10042-76-9) A powerful oxidizer. Reacts violently with reducing agents, acetic anhydride, fert-butylhydroperoxide, metal cyanides, thiocyanates, sodium acetylide. Incompatible with amines, ammonium hexacyanoferrate(II), boranes, cyanides, citric acid, esters, hydrazinium perchlorate, isopropyl chlorocarbonate, nitrosyl perchlorate, organic azides, organic bases, sodium thiosulfate, sulfamic acid. 

Kinetic resolution of secondary allylic alcohols by Sharpless asymmetric epoxidation using fert-butylhydroperoxide in the presence of a chiral titanium-tartrate catalyst has been widely used in the synthesis of chiral natural products. As an extension of this synthetic procedure, the kinetic resolution of a-(2-furfuryl)alkylamides with a modified Sharpless reagent has been used . Thus treatment of racemic A-p-toluenesulphonyl-a-(2-furfuryl)ethylamine [( )-74] with fert-butylhydroperoxide, titanium isopropoxide [Ti(OPr-/)4], calcium hydride (CaHa), silica gel and L-(+)-diisopropyl tartrate [l-(+)-DIPT] gave (S)-Al-p-toluenesulphonyl-a-(2-furfuryl)ethylamine [(S)-74] in high chemical yield and enantiomeric excess . Similarly prepared were the (S)-Al-p-toluenesulphonyl-a-(2-furfuryl)-n-propylamine and other homologues of (S)-74 using l-(+)-D1PT. When D-(—)-DIPT was used, the enantiomers were formed . ... 

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