Ferrocenyl isocyanide

Oxidized ferrocenyl isocyanide ligands, with Fc+ = Fe(rj -C5H5) (rj -C5H4)+,... 

Table 7-6. Formal electrode potentials (vs. SCE) for the two one-electron oxidations exhibited by the ferrocenyl-isocyanide complexes (C5H5)Fe[C5H4-(CHR) NCCr(CO)5] in acetonitrile solution [38, 39]...

The isocyanide monolayer was formed by immersing the Cr slide in a 1 mM isocyanide solution under argon for 30 min. The redox wave, which is observed in cyclic voltammograms of the modified Cr electrode, proves that the 4-ferrocenyl-phenyl isocyanide is adsorbed on the metal surface. When a Cr electrode is exposed for 2 h to a solution of ferrocene, no redox wave was observed in the CV, which demonstrates that the isocyanide group is necessary for adsorption. No spectroscopic studies were performed on the adsorbed isocyanide. 

BIS(CYCLOHEXYL ISOCYANIDE)GOLD(I) f, 2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 115... 

For a more detailed discussion, see Bis(cyclohexyl isocyanide)gold(l) Tetrafluoroborate-(R)-N-[2-(N,N-Dimethylamino)ethyl]-N-methyl-l-[(S)-l, 2-bis diphenylphosphino)ferrocenyl]ethylamine. 

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