Polymers ferrocenes

Figure 26 The transition metal-catalyzed ROP of sila[l]ferrocene in the presence of Si—H functionalized diferrocenylborane to the ferrocene polymer 37. (Adapted from ref. 59.)...

This kind of electronic situation is rather common in ferrocene polymers. In fact, it has been found also in the polymers represented in Scheme 1. 

As far as the electrode adsorption phenomena caused by P° y erro cenes are concerned, Figure 26 shows the cyclic voltammetric response o the illustrated fluorenyl-ferrocene polymer (Fw 7000). 

Abd-El-Aziz, A., Carraher, C., Pittman, C., Sheats, J., and Zeldin, M. 2004. Ferrocene Polymers. Wiley, Hoboken, NJ. 

Ferrocene mediators, in biosensing, 12, 594 Ferrocene polyaromatic dyads, preparation, 6, 189—190 Ferrocene polymer compounds, characteristics, 12, 449 Ferrocene—ruthenocene compounds, preparation, 6, 635 Ferrocenes... 

T. A., Aliev, L. A. Dehydration and Dehydrogenation of Alcohols, Catalyzed by Ferrocene Polymers. Dokl. Akad. Nauk. SSSR 186, 108 (1969). 

In a subsequent investigation by the author [1] a pyrolysis of siloxane-ferrocene polymers, (IV), was used to prepare ceramic materials. 

The disulfide links in the organometallic ferrocene polymers can be reductively cleaved, as in other disulfide-connected structures such as proteins, and the iron centers can be oxidized electrochemically to give ferrocenium units [273] both these redox processes are reversible in principle. 

TABLE 1.2 Glass Transition Temperatures, Tg, of Acrylic Ferrocene Polymers [30]... 

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