Ferrocene-functionalized polymer surface-initiated

Synthesis of ferrocene-functionalized polymer brushes on a gold substrate by simultaneous SI-ATRP and click chemistry. (Reprinted with permission from Xu et al. 2010. One-Pot Preparation of "Ferrocene-Functionalized Polymer Brushes on Gold Substrates by Combined Surface-Initiated Atom Transfer Radical Polymerization and "Click Chemistry." Langmuir 26 (19) 15376-15382, copyright (2010) American Chemical Society.)... [Pg.72]

Graphical representation of the preparation of ferrocene-functionalized polymer brush arrays via SI-ROMP by DPN. (Reproduced from Liu et al. 2(X)3. Surface and site-specific ring-opening metathesis polymerization initiated by dip-pen nanolithography. Angewandte Chemie-lnternational Edition 42 (39) 4785-4789 with permission from Wiley.)... [Pg.75]

A comprehensive summary of the syntheses and applications of the ferrocene polymer brushes has been presented. Ferrocene-functionalized polymer brushes covalently bonded or physisorbed on solid substrate surfaces can be readily prepared via well-known surface modification techniques, such as surface-initiated polymerizations, reaction of the end-functional groups of polymer chains with substrate surfaces, and host-guest interaction. These electroactive polymer brushes have found applications in biosensors, anion-exchange chromatography, and redox-controlled modification of surface wetting properties. [Pg.87]

Kim, B. Y., E. L. Ratcliff, N. R. Armstrong, T. Kowalewski, and J. Pyun. 2010. Ferrocene functional polymer brushes on indium tin oxide via surface-initiated atom transfer radical p>olymerization. 26 (3) 2083-2092. [Pg.89]

Xu, L. Q., D. Wan, H. F. Gong, K. G. Neoh, E. T. Kang, and G. D. Fu. 2010. Qne-p>ot preparation of ferrocene-functionalized polymer brushes on gold substrates by combined surface-initiated atom transfer radical polymerization and "dick chemistry." 26 (19) 15376-15382. [Pg.90]