Fall-off Curves in Thermal Activation

5k and Ac are directly related to measurable quantities, and are easily determined). A comparison of full RRKM and simple reduced Kassel fall-off curves is wn 

Stepladder Modds.— Weak collision effects can, to a first approximation, be taken into account by using a sequence of single down steps instead of one down step for deactivation (see above). For chemical and also optical activation, 

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