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Face-sharing bioctahedral structures

The structure of the mixed hydroxo-alkoxide species consists of two face-sharing bioctahedral Zr2X9 units each bound to Ba2+ by four X groups. Recent studies28 have shown that for the system Al(OPr )3—M(OPr )4, M = Zr and Hf, in isopropanol there is only one type of complex formed, namely, [(OPr )2Al(p,-OPr )2]2M(OPr )2. A rare heterotermetallic alkoxide which contains Cd, Ba, and Zr has been prepared29 according to... [Pg.885]

Veith M, Mathur S, Mathur C, Huch V. Synthesis, reactivity and structure of Hf-containmg homo and hetero-(bi- and tri-) metallic alkoxides based on edge-and face-sharing bioctahedral alkoxometalate ligands. J Chem Soc Dalton Trans 1997 2101-8. [Pg.527]

The ruthenium and osmium binulear complexes discussed in this paper have a face-sharing bioctahedral (FSBO) structure as shown below ... [Pg.504]


See other pages where Face-sharing bioctahedral structures is mentioned: [Pg.746]    [Pg.746]    [Pg.319]    [Pg.106]    [Pg.746]    [Pg.746]    [Pg.319]    [Pg.106]    [Pg.283]    [Pg.244]    [Pg.244]    [Pg.389]    [Pg.291]    [Pg.480]    [Pg.588]    [Pg.621]    [Pg.283]    [Pg.448]    [Pg.394]    [Pg.476]    [Pg.3430]   
See also in sourсe #XX -- [ Pg.247 ]




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