F Chloroethylene

Bis-(2-methoxyethyl) ether, 2549 f 1,3-Butadiene, 1480 f 1,3-Butadiyne, 1385 f 2-Butanol, 1695 f Buten-3-yne, 1423 f Butyl ethyl ether, 2540 f Butyl vinyl ether, 2484 f 2-Chloro-1,3-butadiene, 1451 f Chloroethylene, 0730 f 2-Chloroethyl vinyl ether, 1557... 

Chlorine, Hydrogen( ), Sulfuric acid, 4047 f Chloroethylene, 0730 Ethyl acetate, 1618 Iron, Polystyrene, 4388 Lead(IV) oxide, Metals, 4834 Methylmercuiy perchlorate, 0433 Oxygen (Gas), Biological material, Ether, 4831 Potassium chlorate, Metal phosphinates, 4017 Potassium perchlorate, 4018 Sodium chlorate, Paper, Static electricity, 4039 f Trichlorosilane, 4136... 

Poly(dimethylketene peroxide) f Chloroethylene, 0726 f 1,3-Cyclohexadiene, 2354 f Cyclopentadiene, Oxygen, 1851 f 1,1-Dichloroethylene, 0691 f Diethyl ether, 1691... 

Fliiorothene. A plastic polymer of trifluoro-chloroethylene, C2F3C1. Resistant to coned acids and alkalies up to 300°F. Swelled by some chlorinated hydrocarbons Ref CondChemDict (1961), 507-R (1971), 208-R... 

TRIFLUORO- CHLOROETHYLENE Chlorotrifluoro-ethylene, Kel F monomer, Plaskon monomer, Trifluorovinyl chloride, CTFE Flammable Compressed Gas - 4 0... 

Fluoroplastics. Conventional plasticizers are used as processing aids for fluoroplastics up to alevel of 25% plasticizer. However, certain grades of Kel-F (chlorotrifiuorethylene) contain up to 25 wt % plasticizer to improve elongation and increase softness the plasticizers used are usually low molecular weight oily chloroethylene polymers (5). 

Zajdela F, Croisy A, Barbin A, et al. 1980. Carcinogenicity of chloroethylene oxide, an ultimate reactive metabolite of vinyl chloride, and bis(chloromethyl) ether after subcutaneous administration and in initiation-promotion experiments in mice. Cancer Res 40 352-356. 

Various chlorine-substituted benzenes have been studied extensively by ED and MW and the most accurate results were obtained by joint analyses of ED intensities, rotational constants (from MW or high-resolution IR spectra) and dipolar coupling constants from liquid-crystal NMR spectra. Ab initio calculations have also been performed for some of these derivatives246 (Table 27). The primary interest in these studies is the degree of distortion of the benzene ring caused by chlorine substitution but in this context we will discuss only the variation of the C—Cl bond distances. In chlorobenzene this distance [173.90(23) pm] is very slightly longer than that in chloroethylene [173.0(4) pm], similar to the observation for C—F bonds. In the three disubstituted derivatives the C—Cl bond distances shorten only by a few tenths of a pm and are almost independent of the relative position of the two chlorines. These experimental results are reproduced correctly by the ab... 

CHLOROETHYLENE (75-01-4) Extremely flammable liquefied gas (flash point — 108°F/—78°C). Forms unstable peroxides with atmospheric oxygen, strong oxidizers, and various contaminants possible violent polymerization. Polymerization can occur when heated or on long-term exposure to light. Violent reaction with strong oxidizers or oxides of nitrogen. Contact with copper or other acetylide-forming metals forms sensitive explosive... 

Zajdela, F. et al., Carcinogenicity of chloroethylene oxide, an ultimate reactive metabolite of... 

The assignment was confirmed by examination of poly (vinyl fluoride) free from inverted units. This material was made by reductive dechlorination of poly(l-fluoro-l-chloroethylene) by means of tri-n-butyltin hydride the bulky chlorine atom in the monomer effectively prevents head-to-head growth. The F spectrum of poly (vinyl fluoride) prepared by this indirect route contained only the signals in the range 178-185 ppm. 

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