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Extraction factor, partitioning complexes

Solid-phase microextraction (SPME) was introduced in the early 1990s by Arthur and Pawliszyn. SPME is a simple solvent-free sample preparation method for GC and LC. The extraction is based on the partitioning of the analyte between the organic phase on the fused silica fiber and the matrix. Many factors such as pH, temperature, salt concentration, and stirring affect the equilibrium constant and the equihbration time. Fiber lifetime is a significant issue. SPME fiber is quite sensitive to complex matrix such as... [Pg.638]

A promising application of HDEHP extraction appears to lie in the partitioning of actinides from lanthanides. The TALSPEAK process (Trivalent Actinide Lanthanide Separation by Phosphorus Reagent Extraction from Aqueous Komplexes) involves extraction of Ln s with HDEHP from an aqueous solution of a complex (such as DTPA) which has a high affinity for and represses extraction of the middle and heavier lanthanons and actinide elements most of all . The separation factor between the An s, Am and Cm ", and the Ln s exceeds 100. [Pg.107]

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