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Expanded cross-conjugated systems

Tlie name fulvaleiie was first mentioned by R. Brown (49TFS296), who expanded the class of fulvenes for those compounds containing two cyclic poly-enic systems with a central double bond. Tlius, depending on the ring size, cy-clopropylidenecyclopropene 1, fulvaleiie 2, heptafulvalene 3 and the unsymmetrical hybrid molecules triapentafulvalene (calicene) 4, triaheptaful-valene 5, and pentaheptafulvalene (sesquifulvalene) 6 are members of this class of cyclic cross-conjugated systems (Scheme 1). [Pg.116]

In 1982 the present author discovered cyclic orbital interactions in acyclic conjugation, and showed that the orbital phase continuity controls acyclic systems as well as the cyclic systems [23]. The orbital phase theory has thus far expanded and is still expanding the scope of its applications. Among some typical examples are included relative stabilities of cross vs linear polyenes and conjugated diradicals in the singlet and triplet states, spin preference of diradicals, regioselectivities, conformational stabilities, acute coordination angle in metal complexes, and so on. [Pg.22]


See other pages where Expanded cross-conjugated systems is mentioned: [Pg.328]    [Pg.337]    [Pg.328]    [Pg.337]    [Pg.205]    [Pg.185]    [Pg.18]    [Pg.337]    [Pg.338]    [Pg.340]    [Pg.343]    [Pg.344]    [Pg.346]    [Pg.348]    [Pg.349]    [Pg.350]    [Pg.352]    [Pg.352]    [Pg.354]    [Pg.356]    [Pg.358]    [Pg.360]    [Pg.362]    [Pg.43]    [Pg.106]    [Pg.2]    [Pg.162]    [Pg.142]    [Pg.378]    [Pg.603]   


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Conjugate system

Conjugated system conjugation)

Conjugated systems

Conjugation cross

Cross-Conjugation in Expanded Systems

Cross-conjugated

Systems expandability

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