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Exchange reactions between uranium ions

The exchange reaction between U(VI) and U(IV) in aqueous sulphate chloride and perchlorate media and in various mixed aqueous-organic solvents [Pg.130]

Betts obtained evidence for the exchange in sulphate media being catalysed by light of wavelengths 340 m/t, the region of absorption of U(VI). In the presence of light a rate law, approximately [Pg.131]

The rate was found to be unaffected by light and either [Cl ] or [CIO4 ]. The overall activation energy obtained was 33.4 kcal.mole . The mechanism of exchange suggested by Rona was [Pg.131]

Masters and Schwartz have made a study of the exchange in perchlorate media and have found two exchange pathways operate. One pathway involves exchange via the process [Pg.131]

IONS OF SAME METAL IN DIFFERENT OXIDATION STATES [Pg.132]


See other pages where Exchange reactions between uranium ions is mentioned: [Pg.130]    [Pg.151]    [Pg.130]    [Pg.151]    [Pg.131]    [Pg.128]    [Pg.240]    [Pg.1059]    [Pg.144]    [Pg.557]    [Pg.697]    [Pg.1059]    [Pg.234]    [Pg.557]    [Pg.2328]    [Pg.2423]    [Pg.4206]    [Pg.245]    [Pg.245]    [Pg.508]    [Pg.2423]   


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