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Ethylmalonyl chloride

Acylation takes place similarly with a,/3-unsaturated acid chlorides such as 92 (260) and with ethylmalonyl chloride (93) (130) (Scheme 65). [Pg.49]

Cool the solution to 0°C and slowly add 1 g of ethylmalonyl chloride (Aldrich) under nitrogen with stirring. [Pg.634]

Figure 15.9 The reaction of the amine-blocked derivative of 3-hydroxypropylamine with ethylmalonyl chloride gives an ethylmalonate-protected-amine compound, which can be used in the Bingel reaction to create an amine group on a fullerene surface. Reaction with Cfl in the presence of I2 and DBU gives the cyclopropanation product that can be deprotected with TFA to yield the free amine. Figure 15.9 The reaction of the amine-blocked derivative of 3-hydroxypropylamine with ethylmalonyl chloride gives an ethylmalonate-protected-amine compound, which can be used in the Bingel reaction to create an amine group on a fullerene surface. Reaction with Cfl in the presence of I2 and DBU gives the cyclopropanation product that can be deprotected with TFA to yield the free amine.
See other pages where Ethylmalonyl chloride is mentioned: [Pg.636]    [Pg.636]   
See also in sourсe #XX -- [ Pg.634 ]



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