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Ethylene glycol monoformate

Photolytic. Grosjean (1997) reported a rate constant of 1.87 x lO " cm /molecule-sec at 298 K for the reaction of 2-ethoxyethanol and OH radicals in the atmosphere. Based on an atmospheric OH radical concentration of 1.0 x 10 molecule/cm , the reported half-life of methanol is 0.35 d (Grosjean, 1997). Stemmier et al. (1996) reported a rate constant of 1.66 x 10 " cm /molecule-sec for the OH radical-initiated oxidation of 2-ethoxyethanol in synthetic air at 297 K and 750 mmHg. Major reaction products identified by GC/MS (with their yields) were ethyl formate, 34% ethylene glycol monoformate, 36% ethylene glycol monoacetate, 7.8% and ethoxyacetaldehyde, 24%. [Pg.551]

Ethylene glycol diformate, see 1,4-Dioxane Ethylene glycol monoacetate, see 2-Ethoxyethanol Ethylene glycol monoformate, see 2-Ethoxyethanol Ethylene oxide, see 1,2-Dichloroethane, Ethylene dibromide... [Pg.1529]

Fig. 5. Plot of log(rates) vs. log(pressure) for rhodium-catalyzed CO hydrogenation. Reaction conditions 75 ml sulfolane, 3 mmol Rh, 1.25 mmol pyridine, H2/CO = 1, 240 C, 4 hr (96). Total rate includes rates to methanol, methyl formate, ethanol, ethylene glycol monoformate, and propylene glycol ( ) total ( ) methanol ( ) ethylene glycol. Open figures are for an experiment with H2/CO = 0.67. Fig. 5. Plot of log(rates) vs. log(pressure) for rhodium-catalyzed CO hydrogenation. Reaction conditions 75 ml sulfolane, 3 mmol Rh, 1.25 mmol pyridine, H2/CO = 1, 240 C, 4 hr (96). Total rate includes rates to methanol, methyl formate, ethanol, ethylene glycol monoformate, and propylene glycol ( ) total ( ) methanol ( ) ethylene glycol. Open figures are for an experiment with H2/CO = 0.67.
Hydrogen per oxide formic acid Ketones from ethylene derivatives via glycol monoformates Indanones from indenes... [Pg.346]

See other pages where Ethylene glycol monoformate is mentioned: [Pg.329]    [Pg.348]    [Pg.351]    [Pg.51]    [Pg.179]    [Pg.515]    [Pg.179]    [Pg.515]    [Pg.256]    [Pg.256]    [Pg.346]    [Pg.329]    [Pg.348]    [Pg.351]    [Pg.51]    [Pg.179]    [Pg.515]    [Pg.179]    [Pg.515]    [Pg.256]    [Pg.256]    [Pg.346]   
See also in sourсe #XX -- [ Pg.138 , Pg.256 ]



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