Ethyl hypochlorite

Ghlorohydrination with er -All l Hypohalites. Olefins react with ethyl hypochlorite [624-85-1] to form the corresponding chlorohydrin (49). In 1938 both Shell Development Co. (50) and Arthur D. Litde, Inc. (51) patented the preparation of chlorohydrins by the reactions of olefins with tertiary alkyl hypochlorites. Examples with ethylene and propylene in the Shell patent reported chlorohydrin yields of greater than 95% with tert-huty hypochlorite [507-40-4]. 

This dialkoxydiphenylsulfurane has been prepared by the reaction of diphenyl sulfide, 2,2,2-trifluoro-l-phenyl-l-(trifluoromethyl)ethyl hypochlorite, and potassium l,l,l,3,3,3-hexafluoro-2-phenyl-2-propanolate and by the reaction of diphenyl sulfide with 1 equivalent of chlorine and 2 equivalents of potassium 1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate in diethyl ether. ... 

Chloroperoxytrifluoromethane, 0319 Chloiyl hypofluorite, 3973 Difluoromethylene dihypofluorite Ethyl hypochlorite, 0851 Fluorine perchlorate, 3976 Heptafluoroisopropyl hypofluorite, 1035 Heptafluoropropyl hypofluorite, 1060 Hypochlorous acid, 3995... 

Ethyl Hypochlorite. CH3CH2C1 mw 80.52, OB to C02 and Cl2 -109.3%, d=1.013 at 6°, bp 36° at 758mm. Yellow, volatile, oily liquid was prepd in 1885 by Sandmeyer (Ref 3) by bubbling C102 through cold ethanol or by mixing a cold aq, solution of HCIO with cold ethanol... 

M.M- Thacker, H.O. Folkins, USP 2460200(1949) CA 45, 10565(1951) (Addition of small quantities of explosives, such as Ethyl Hypochlorite, TNT Benzazide etc to the hydrocarbons undergoing cracking, increases the yields of desirable products, permits carrying the reaction at lower temp and in shorter time)... 

Ethyl hypochlorite, C2H5OCl, is a substance that is decomposed with explosion when irradiated by sun-light or brought into contact with copper dust. Methyl hypochlorite, boiling at 12°C, also exhibits similar properties. 

Ethyl hypochlorite is a yellow liquid, the boiling point of which is 36°C (Sandmeyer [1]). It was prepared by introducing chlorine gas into a cooled mixture composed of 1 part of sodium hydroxide, 1 part of ethanol and 9 parts of water. 

Chloroperoxytrifluoromethane, 0318 Chloryl hypofluorite, 3967 Difluoromethylene dihypofluorite, 0354 Ethyl hypochlorite, 0847... 

Traugott Sandmeyer described the synthesis of methyl and ethyl hypochlorites (refs. 2, 3) and suffered severe injuries. 

Organic halides of other elements [tin (43-45), phosphorus (6,54), nitrogen (46,93,245,251), sulfur (232,233,252,256-259)1 also participateV in Michaelis-Arbuzov type reactions. Heating the organic lead compound EtsPbBr with (EtO)3P at 100° gave only an unidentified white amorphous solid (45). Petrov and SokoPskii (250), who observed the formation of phosphate esters from the reactions of ethyl hypochlorite with various phosphite esters, proposed the existence of a pentacovalent intermediate which decomposed by loss of alkyl halide. 

TRIFLUOROMETHYL HYPOCHLORITE AND PERFLUORO-tert-BUTYL HYPOCHLORITE (2,2,2-TRIFLUORO-l,l-BIS(TRIFLUOROMETHYL)ETHYL HYPOCHLORITE)... 

Likewise, addition of ethyl hypochlorite to isocyanides yields the chloroimidates LVII... 

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