Ethyl 4-amino-3-methylbenzoate

Ethyl 4-amino-3-methylbenzoate has been reported previously.7... 

B. Ethyl l-Amino-S-methylbenzoate. A 1-1., three-nocked, round-bottomed flask equipped with a mechanical stirrer, a condenser, and a nitrogen-inlet tube is charged with 11.25 g. (0.050 mole) of ethyl 4-amino-3-(methylthiomethyl)benzoate, 300 ml. of absolute ethanol, and 17 teaspoons (ca. 50 g.) of W-2 Raney nickel (Note 7). The reaction mixture is stirred at 25° for one hour, then stirring is discontinued, and the ethanolic solution is decanted from the catalyst (Note 8). The catalyst is then washed with one 300-ml. portion of absolute ethanol and one 500-ml. portion of dichloromethane, the solvent being removed... 

C8H9N02 2-amino-6-methylbenzoic acid 4389-50-8 19.47 1.1446 2 13882 C8H10N2O2 N-ethyl-2-nitroaniline 10112-15-9 25.00 1.1900 1... 

C8H9N02 4-amino-3-methylbenzoic acid 2486-70-6 518.92 45.705 2 13825 1 C8H10CIN 2-(3-chlorophenyl)ethyl amine 13078-79-0 501.03 43.983 2... 

B. Ethyl i-Amino-Z-methylbenzoate. A 1-1., three-necked, round-bottomed flask equipped with a mechanical stirrer, a condenser, and a nitrogen-inlet tube is charged with 11.25 g. (0.050 mole) of ethyl... 

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