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Ethyl acetoacetate alcohol isolation

In 1940, the reaction was unexpectedly discovered by M. F. Carroll while attempting the acetylation of various allylic alcohols. When cinnamyl alcohol (186) was treated with ethyl acetoacetate (185) in the presence of catalytic sodium acetate, the anticipated acetate 187 was not formed via a retro-Claisen condensation. However, the methyl ketone 189 was isolated. [Pg.52]


See other pages where Ethyl acetoacetate alcohol isolation is mentioned: [Pg.482]    [Pg.288]    [Pg.482]    [Pg.104]    [Pg.482]    [Pg.288]    [Pg.288]    [Pg.177]    [Pg.201]    [Pg.272]    [Pg.482]    [Pg.482]    [Pg.722]    [Pg.88]    [Pg.444]   
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