Equilibria of dioxygen complexes

Dioxygen binding may be reversible or irreversible. If binding is reversible, bound dioxygen can be removed by changing the temperature, partial pressure of 0 gas, pH, solvent, etc. Removal of 0 must result [Pg.37]

When one half of the metal complex is oxygenated, the above expressions can be written as [Pg.37]

Parent complex Dioxygen P (Cl ) Complex Torr Conditions [Refs.] [Pg.39]

Co(TPivPP)(Me2lm) Picket fence porphyrin, CoO 900 25 °C, toluene [266] [Pg.39]

Fe(Durene-4,4) Fe(Durene-5, 5) Fe(Durene-7, 7) Durene-capped porphyrins FeO (structure 23) 7.7x10 2.1x10 7.7x10 —A 0 20 C,benzene , or toluene -4 [369] [Pg.39]

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