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Epoxidation single molecule studies

Effects of hydroxylic solvents on epoxidation of styrene with H2O2 have been studied. Consistent results were obtained when the impact of a single molecule of water, ethanol, and t-BuOH on the reaction was simulated using the discrete model. Reactivity was greatest for /-BuOH followed by ethanol protic solvent molecules promote the heterolytic cleavage of H2O2 and form active oxygen species that reduce the reaction barrier. ... [Pg.143]

See other pages where Epoxidation single molecule studies is mentioned: [Pg.155]    [Pg.73]    [Pg.75]    [Pg.127]    [Pg.57]    [Pg.1384]    [Pg.362]    [Pg.75]    [Pg.162]    [Pg.21]    [Pg.274]    [Pg.345]    [Pg.644]    [Pg.482]    [Pg.418]    [Pg.179]    [Pg.261]    [Pg.334]    [Pg.277]    [Pg.346]    [Pg.381]    [Pg.359]    [Pg.31]    [Pg.212]   
See also in sourсe #XX -- [ Pg.155 ]



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