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Epoxidation chelate-directed

The direct resolution of underivatised enantiomers has been effected with the aid of some metal-containing chiral stationary phases. Particular attention has been paid to the resolution of chiral alkenes and epoxides using stationary phases derived from chiral metal chelate complexes. The rhodium dicarbonyl P-diketonate complex (5), when dissolved in squalene and coated onto a capillary column, permitted the quantitative enantiomer resolution of 3-methylcyclopentene while methyl oxirane was similarly resolved... [Pg.39]

See other pages where Epoxidation chelate-directed is mentioned: [Pg.51]    [Pg.51]    [Pg.51]    [Pg.298]    [Pg.380]    [Pg.646]    [Pg.646]    [Pg.118]    [Pg.12]    [Pg.199]    [Pg.199]    [Pg.144]    [Pg.219]    [Pg.199]    [Pg.23]    [Pg.530]    [Pg.833]    [Pg.833]    [Pg.388]    [Pg.516]    [Pg.434]    [Pg.434]    [Pg.177]    [Pg.499]    [Pg.512]    [Pg.14]    [Pg.52]    [Pg.47]    [Pg.42]    [Pg.81]    [Pg.833]    [Pg.52]    [Pg.99]    [Pg.117]    [Pg.342]    [Pg.434]   
See also in sourсe #XX -- [ Pg.298 , Pg.302 ]



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Epoxides directed epoxidation

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