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A third form of the fundamental equation will be useful when we come to discuss the statistical mechanics in Chapter 4. The free energy F is the proper thermodynamic function to associate with the (petit) canonical ensemUe, but it is often more convenient to work with die grand canonical ensemble, for whidi the appropriate potential is O, where... [Pg.30]

See other pages where Ensemble petit canonical is mentioned: [Pg.227] [Pg.227] [Pg.482] [Pg.218] [Pg.87] [Pg.103] [Pg.103] [Pg.251] [Pg.308]