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Enones, absorption wavelength

Table 7.9 Electronic Absorption Bands for Representative Chromophores Table 7.10 Ultraviolet Cutoffs of Spectrograde Solvents Table 7.11 Absorption Wavelength of Dienes Table 7.12 Absorption Wavelength of Enones and Dienones Table 7.13 Solvent Correction for Ultraviolet-Visible Spectroscopy Table 7.14 Primary Bands of Substituted Benzene and Heteroaromatics Table 7.15 Wavelength Calculation of the Principal Band of Substituted Benzene Derivatives... Table 7.9 Electronic Absorption Bands for Representative Chromophores Table 7.10 Ultraviolet Cutoffs of Spectrograde Solvents Table 7.11 Absorption Wavelength of Dienes Table 7.12 Absorption Wavelength of Enones and Dienones Table 7.13 Solvent Correction for Ultraviolet-Visible Spectroscopy Table 7.14 Primary Bands of Substituted Benzene and Heteroaromatics Table 7.15 Wavelength Calculation of the Principal Band of Substituted Benzene Derivatives...
Sets of empirical rules, often referred to as Woodward s rules or the Woodward-Fieser rules, enable the absorption maxima of dienes (Table 7.11) and enones and dienones (Table 7.12) to be predicted. To the respective base values (absorption wavelength of parent compound) are added the increments for the structural features or substituent groups present. When necessary, a solvent correction is also applied (Table 7.13). [Pg.707]

Tables 6.3-6.5 record data developed to undertake structural analysis in systems possessing chromophores that are conjugated or otherwise interact with each other. Chromophores within a molecule interact when linked directly to each other or when they are forced into proximity owing to structural constraints. Certain combinations of functional groups comprise chromophoric systems that exhibit characteristic absorption bands. In the era when UV-VIS was one of the principal spectral methods available to the organic chemist, sets of empirical rules were developed to extract as much information as possible from the spectra. The correlations referred to as Woodward s rules or the Woodward-Fieser rules, enable the absorption maxima of dienes (Table 6.3) and enones and dienones (Table 6.4) to be predicted. When this method is applied, wavelength increments correlated to structural features are added to the respective base values (absorption wavelength of parent compound). The data refer to spectra determined in methanol or ethanol. When other solvents are used, a numerical correction must be applied. These corrections are recorded in Table 6.5. Tables 6.3-6.5 record data developed to undertake structural analysis in systems possessing chromophores that are conjugated or otherwise interact with each other. Chromophores within a molecule interact when linked directly to each other or when they are forced into proximity owing to structural constraints. Certain combinations of functional groups comprise chromophoric systems that exhibit characteristic absorption bands. In the era when UV-VIS was one of the principal spectral methods available to the organic chemist, sets of empirical rules were developed to extract as much information as possible from the spectra. The correlations referred to as Woodward s rules or the Woodward-Fieser rules, enable the absorption maxima of dienes (Table 6.3) and enones and dienones (Table 6.4) to be predicted. When this method is applied, wavelength increments correlated to structural features are added to the respective base values (absorption wavelength of parent compound). The data refer to spectra determined in methanol or ethanol. When other solvents are used, a numerical correction must be applied. These corrections are recorded in Table 6.5.
TABLE 6.4 Absorption Wavelength of Enones and Dienones (continued)... [Pg.658]

The wavelengths of maximum absorption of conjugated dienes and polyenes and conjugated enones and dienones are given by the Woodward and Fieser Rules, Tables 1 and 2. [Pg.237]

Effect of Photooxidation on the Luminescent a,/ -Unsaturated Carbonyl Groups. The longest wavelength n —w absorption bands (15,16, 17) of both the enone and dienone chromophoric impurities overlap the high energy end of the spectrum of natural sunlight known to be harmful to the commercial polyolefins (20,21) (i.e., 300-350 nm). [Pg.78]

Cf,/ -Unsaturated aldehydes generally follow the same rules as enones (see the preceding section) except that their absorptions are displaced by about 5 to 8 nm toward shorter wavelength than those of the corresponding ketones. Table 7.8 lists the empirical rules for unsaturated aldehydes. [Pg.374]


See other pages where Enones, absorption wavelength is mentioned: [Pg.711]    [Pg.959]    [Pg.980]    [Pg.651]    [Pg.657]    [Pg.325]    [Pg.310]    [Pg.318]    [Pg.320]    [Pg.163]    [Pg.167]    [Pg.168]    [Pg.173]    [Pg.182]    [Pg.219]    [Pg.219]    [Pg.818]    [Pg.250]    [Pg.287]    [Pg.386]    [Pg.610]    [Pg.1436]    [Pg.414]   
See also in sourсe #XX -- [ Pg.7 , Pg.22 ]

See also in sourсe #XX -- [ Pg.7 , Pg.22 ]




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Absorption wavelength

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