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Enone Cycloadditions and Rearrangements

IntraBolecular.- The apnide (1) is converted on irradiation in benzene/ethanol into a complex mixture of products (2)-(5). [Pg.173]

A previous report gave an account of the intramolecular photocyclization of the enone (12) to afford the head-to-head adduct (13). The adduct (13) obtained in this way has been used as a starting material for pentalenolaotone G methyl ester (14). While the above reaction only yields a [Pg.173]

A 70X yield of the adduct (24) is obtained on brief irradiation through Pyrex of a hexane solution of the enone [Pg.179]

The intramolecular photoaddition of the enone (32) in chlorobenzene using wavelengths 350 nm affords the adducts [Pg.179]

An efficient route to the synthesis of the cycloalkanones (37) involving the intramolecular photochemical cyclization of the enones (38) has been described. This yields the tricyclic [Pg.179]


Enone Cycloadditions and Rearrangements Photoreactions of Dienones and Quinones... [Pg.233]


See other pages where Enone Cycloadditions and Rearrangements is mentioned: [Pg.530]    [Pg.530]    [Pg.235]    [Pg.237]    [Pg.239]    [Pg.241]    [Pg.243]    [Pg.245]    [Pg.247]    [Pg.249]    [Pg.251]    [Pg.253]    [Pg.255]    [Pg.259]    [Pg.261]    [Pg.263]    [Pg.265]    [Pg.267]    [Pg.269]    [Pg.271]    [Pg.273]    [Pg.530]    [Pg.175]    [Pg.177]    [Pg.179]    [Pg.181]    [Pg.183]    [Pg.185]    [Pg.187]    [Pg.189]    [Pg.191]    [Pg.193]    [Pg.195]    [Pg.197]    [Pg.199]    [Pg.201]    [Pg.203]    [Pg.205]    [Pg.207]    [Pg.209]    [Pg.211]    [Pg.213]    [Pg.215]    [Pg.217]    [Pg.219]    [Pg.221]    [Pg.223]    [Pg.225]    [Pg.227]   


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Cycloaddition and

Cycloaddition/rearrangement

Enone Rearrangements

Enone cycloadditions

Enones rearrangement

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