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Enolate anions configurational stability

The preferential -configuration of the enol esters, derived from p-dicarbonyl compounds under phase-transfer conditions, contrasts with the formation of the Z-enol esters when the reaction is carried out by classical procedures using alkali metal alkoxides. In the latter case, the U form of the intermediate enolate anion is stabilized by chelation with the alkali metal cation, thereby promoting the exclusive formation of the Z-enol ester (9) (Scheme 3.5), whereas the formation of the ion-pair with the quaternary ammonium cation allows the carbanion to adopt the thermodynamically more stable sickle or W forms, (7) and (8), which lead to the E-enol esters (10) [54],... [Pg.96]

A rare species of salts consisting of a heteroatom-stabilized carbocation and a heteroatom-stabibzed carbanion has been formed by deprotonating methyl (Z)- or (E)-3-hydroxy-2,3-dimesitylpropenoate with tetrakis(dimethylamino)methane the resonance stabilization of the cation [(CH3)2N]3C+ and enolate anion, which is of E-configuration exclusively, since the guanadinium ion is incapable of forming a chelate, prevents a spontaneous O- or C-alkylation.12... [Pg.330]

There are two other reactive species whose cis-trans isomerism can be important to the distribution of products, organometallics derived from vinyl halides, and enolate anions. The configurational stability of these species will be discussed in detail in Sections 8.4.F, 8.5.D and in Sections 9.2.C, 9.5, respectively. The... [Pg.497]


See other pages where Enolate anions configurational stability is mentioned: [Pg.773]    [Pg.622]    [Pg.28]    [Pg.509]    [Pg.319]    [Pg.36]    [Pg.21]    [Pg.758]    [Pg.758]    [Pg.254]    [Pg.2085]    [Pg.395]    [Pg.263]    [Pg.758]    [Pg.2084]    [Pg.511]    [Pg.327]    [Pg.13]   
See also in sourсe #XX -- [ Pg.498 ]




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Anion stabilization

Configurational stability enolates

Enol configuration

Enolate Stabilized

Enolate anions

Enolates anion

Enolates anionic

Enolates stabilization

Enolates stabilized

Enolates stabilizing

Enols stability

Stability configuration

Stability enolate

Stability enolates

Stabilized Enols

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