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Enol ethers reaction with benzeneselenenyl chloride

The addition of selenium electrophiles to activated ir-bonds (i.e. enol ethers) occurs readily. Enol ethers react with benzeneselenenyl chloride to produce cis- and tranj-a-chloro-P-phenylseleno adducts. These adducts can be transformed into a,p-dichlorides or allylic chlorides. If the reaction is carried out in the presence of alcohols, stereoisomers of P-seleno mixed ketals are isolated (equation 12). °... [Pg.520]


See also in sourсe #XX -- [ Pg.520 ]

See also in sourсe #XX -- [ Pg.520 ]

See also in sourсe #XX -- [ Pg.520 ]




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Benzeneselenenyl chlorides, reactions with

Enol ethers chloride

Enols reactions with

Reaction with ethers

Reactions, with enol ethers

Reactions, with enolates

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