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Energy-rich collision intermediate

As noted in Section 3.1, the termolecular reaction A + B + M — AB + M does not take place as the result of the simultaneous collision of A, B, and M rather, A and B react to form an energy-rich intermediate AB1 that subsequently collides with a third molecule M (the reaction chaperone), which removes the excess energy and allows formation of AB. (The dagger denotes vibrational excitation.)... [Pg.85]

It can readily be seen why an energy-rich intermediate species must participate. In the dissociation direction, reaction can only occur after the molecule AB has accumulated, through collisions, enough energy to rupture the chemical bond holding A and B together in the recombination direction, the first species formed in an A-B encounter retains all of the energy of the newly formed bond until later events, i.e., subsequent collisions, cause it to be dissipated to the environment. [Pg.177]

At the time of the conference the study of nuclear reactions produced by intermediate energy protons or pions as well as the investigation of collisions between two nuclei of Z 2= 3 were still in a rather primitive stage whereas today they constitute a rich field of empirical knowledge and phenomenological interpretation. [Pg.28]


See other pages where Energy-rich collision intermediate is mentioned: [Pg.187]    [Pg.55]    [Pg.15]    [Pg.450]    [Pg.282]    [Pg.240]    [Pg.313]   
See also in sourсe #XX -- [ Pg.15 , Pg.186 , Pg.215 ]




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