Energetic diagram

Figure 5.14. Energetic diagram of formation of ion AB+ from ABXY molecule.

Figure 3.44. The energetic diagram for reaction (I) is to the left and for reaction (II) to the right. States not participating in the transfer reactions are shown by dashed lines.

Fig. 16.11 Energetic diagram of amorphous- and crystaUine-WOs/TiCh [Reprinted from Higashimoto et al. (2006), Copyright (2006), with permission from Elsevier]...

Figure 5 Electronic energetic diagram ofthe molecular orbitals of three-electron bonds in sulphur radicals and optical transition. X S, N, or O atom.

Fig. 14. Energetic diagram of possible channels of C2H5 + 02 reaction and corresponding barriers.

Figure I. Energetics diagram r decomposition of rotatiofudly cold...

Figure 24 shows some examples in an energetic diagram. It shows the case in which an oxide can be oxidized before anodic oxygen evolution (CU2O to CuO), since the conditions (1) and (3) are full filled. In case of Ni(OH)2, Uox > Uq2> but the oxygen evolution is strongly hindered, while the oxidation is fast. Hence, the oxide oxidation takes place in spite of the fact that rule (2) is not fulfilled. 

Fig. 24 Energetic diagram for competition between different redox processes of the oxide and other redox reactions, for example, evolution of hydrogen or oxygen.

Figure 10.35. Energetic diagram of the different oxygen species taken into account...

Location of the localized states related to divalent and trivalent rare-earth ions relative to the valence and conduction bands of the host lattice is one of the most important factors that control the luminescence properties of rare-earth ions in solids. The location of the ground states of Ln ions with respect to the valence band can be estimated from the energies of the charge-transfer transitions (CTT), which are responsible for the broad bands in the excitation spectra of Ln ions. CTT is considered to be a transition of an electron fi om figands to the Ln ion. In the energetic diagram, it corresponds to the transition fi om the top of the valence band to the Ln " " level. The location of Ln " " can be estimated if the energy of the ionization transition (IT) is known. The IT is the opposite process to the CTT and corresponds to the transition of an electron from the Ln ion to the conduction band. 

Figure 24.10 Energetic diagram for the Ba + CHaF- BaF + CHs system. The Left column shows the barium electronic energy levels, and the BaF energy levels on the right the centre column displays an approximate location of the Ba - FCH3 electronic states. Energy values in eV. Adapted from Farmanara et ai, Chem. Phys. Lett., 1999, 304 127, with permission of Elsevier...

Figure 24.22 Left energetic diagram for the l2 - -Ne system both I-I and l2 - Ne distances are considered. Notice how vibrationaLLy excited states are isoenergetic with continuum states of the unbound fragments, which leads to vibrational predissociation. Right pump and probe scheme to estimate the lifetime of the excited l2- Ne complex. Reproduced from WiUberg et al, 3. Chem. Phys., 1992, 96 198, with permission of the American Institute of Physics...

Fig. 8.8. Apparent energetic diagrams of the intramolecular transitions in the foldingunfolding of BPTL Species I and II refer to the single and two-disulfide bond intermediates (see Fig. 8.7). The relative free energies of the reduced and native states depend on the stabilities...

---