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End-group initiation first-order and disproportionation termination narrow distribution

4 End-group initiation first-order and disproportionation termination narrow distribution [Pg.21]

There is no decrease in the number of molecules since only the [Pg.21]

This solution does not hold for a wide distribution, since complete loss of the shorter molecules may occur even for low zip length and eqn. (47) is not valid. [Pg.22]

Rn molecules are rare and the last two terms of eqn. (16) disappear. Then [Pg.22]

The degree of polymerization x at time t is independent of the initial distribution in all cases since [Pg.22]




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And disproportionation

End distribution

End terminations

End-group

First-order termination

Group order

Initiating groups

Initiator end groups

Narrow

Ordering distribution

Terminal groups

Termination, disproportionation

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