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Elements of Rayleigh-Schrodinger RS Perturbation Theory

Since this important method of approximation is fully described elsewhere (Magnasco, 2007,2009a), we limit ourselves here to the main elements of the RS theory for stationary states. [Pg.149]

We now expand both eigenvalue E and eigenfunction ip into powers of X  [Pg.150]

Because of the Hermitian property of Ho, bracketing Equations (4.7) on the left by (t/r01, all the first terms in the RS equations are zero, and we are left with  [Pg.150]


Elements of Rayleigh-Schrodinger (RS) Perturbation Theory Molecular Interactions... [Pg.147]


See other pages where Elements of Rayleigh-Schrodinger RS Perturbation Theory is mentioned: [Pg.147]    [Pg.149]    [Pg.149]   


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RS perturbation theory

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Rayleigh-Schrodinger perturbation

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