Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Electronic wave functions of homonuclear diatomic molecules

In Section 1.19 we classified the electronic wave functions of homonuclear diatomic molecules as g or u, according to whether they were even or odd with respect to inversion g and u refer to inversion of the electronic coordinates with respect to the molecule-fixed axes. This is to be distinguished from the inversion of electronic and nuclear coordinates with respect to space-fixed axes, which was discussed in this section. The electronic Hamiltonian for a diatomic molecule is... [Pg.94]

We have seen that the electronic wave functions of homonuclear diatomic molecules can be classified as g or m, according to their parity. Hence a homonuclear diatomic molecule has a zero permanent electric dipole moment, a not too astonishing result. The same holds true for any molecule with a center of symmetry. The electric dipole-moment operator for a molecule includes summation over both the electronic and nuclear charges ... [Pg.425]

The electronic wave functions of homonuclear diatomic molecules can be approximated as products of LCAOMOs. [Pg.823]


See also in sourсe #XX -- [ Pg.823 ]




SEARCH



Electron functionalization

Electronic of molecules

Electronic wave function

Functional molecules

Homonuclear

Homonuclear diatomic

Homonuclear diatomic electronic

Homonuclear diatomic molecule

Homonuclear diatomic molecules, electron

Homonuclear diatoms

Homonuclear, molecules

Molecule electronic

Molecule function

Molecules homonuclear diatomics

Waves electrons

© 2024 chempedia.info