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Electronic configuration, Mossbauer characterization

Recently, iron(V) nitride complex [PhB( Bulm)3Fe =N]BArF24 (PhB( Bulm)3 = phenyltris(3-tert-butylimidazol-2-ylidene)borato BArp24 = B(3,5-(CF3)2QH3)4 ) has been prepared [100]. This complex has a four-coordinate iron ion with a terminal nitride ligand. The characterization of the complex by Mossbauer and electron paramagnetic resonance spectroscopy demonstrated d iron(V) metal center in a low-spin (S= 1/2) electron configuration. The decomposition of the complex by water at low temperature formed ammonia and iron(ll) species. [Pg.511]

See other pages where Electronic configuration, Mossbauer characterization is mentioned: [Pg.439]    [Pg.486]    [Pg.490]    [Pg.262]    [Pg.1261]    [Pg.1959]    [Pg.2121]    [Pg.2152]    [Pg.1958]    [Pg.1261]    [Pg.4715]    [Pg.95]    [Pg.105]    [Pg.287]    [Pg.435]    [Pg.236]    [Pg.2833]    [Pg.139]    [Pg.2120]    [Pg.2832]    [Pg.236]    [Pg.3690]    [Pg.170]    [Pg.260]    [Pg.595]   
See also in sourсe #XX -- [ Pg.173 ]



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Electron characterization

Electronic Characterization

Mossbauer characterizations

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