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Electron Transfer at Electrodes and Interfaces

An important subject in this chapter on Electron transfer at electrodes and interfaces is to draw an analogy between electrochemical and interfacial electron transfer between two solid phases. Any theory dealing with electron transfer has a thermodynamic and a kinetic basis. In Section 4.2, it was shown that electrons flow or tunnel in the direction of decreasing electrochemical potential the gradient of the electrochemical potential is the driving force behind a directed flow of electrons,... [Pg.220]

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