Electrochemical impedance spectroscopy geometry

Martin Fleischmann was an electrochemical impresario, who conducted his exploration of the subject with all of the skill and knowledge of a master symphony maestro. His many, impressive accomplishments are cataloged in this book and in the scientific literature, and serve as a beacon for those who follow in his footsteps. Although Martin did not use impedance methods extensively in his own work, he did use electrochemical impedance spectroscopy (EIS) to explore electrochemical processes at electrodes of different geometries [1,2]. However, it was his masterful treatment of electrochemical reaction mechanisms that forges the link between Martin s work and that of others who seek to define reaction mechanisms using impedance techniques. 

I. Frateur, V. Mei-Wen Huang, M. E. Orazem, N. Pebere, B. Tribollet, V. Vivier, Local electrochemical impedance spectroscopy Considerations about the cell geometry, Electrochim. Acta, 2008,53, pp. 7386-7395. 

---