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Electrochemical generation and reaction of zinc reagents

JACQUES Pf RICHON, CORINNE GOSMINI, and YOLANDE ROLLIN [Pg.139]

We can alternatively envision the reduction of the organic halide in the presence of Zn(II) (Equation 8.2). [Pg.139]

However most organic halides are less easily reduced than Zn(II). So such a process can only be applied if one is able to catalyse the electroreduction of RX. This can be achieved by electrochemically formed zerovalent nickel complexes. Thus Ni(II)-2,2 -bipyridine (Ni-bpy) compounds can catalyse the electroreduction of alkyl and aryl halides1 at potential more positive than [Pg.139]


Electrochemical generation and reaction of zinc reagents Equipment... [Pg.155]


See other pages where Electrochemical generation and reaction of zinc reagents is mentioned: [Pg.755]    [Pg.757]    [Pg.759]    [Pg.761]    [Pg.763]    [Pg.765]    [Pg.767]    [Pg.769]    [Pg.771]    [Pg.773]    [Pg.775]    [Pg.777]    [Pg.779]    [Pg.781]    [Pg.783]    [Pg.785]    [Pg.787]    [Pg.789]    [Pg.791]    [Pg.793]    [Pg.795]    [Pg.139]    [Pg.141]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]   


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