Electrical double layer INDEX

In situ Fourier transform infrared and in situ infrared reflection spectroscopies have been used to study the electrical double layer structure and adsorption of various species at low-index single-crystal faces of Au, Pt, and other electrodes.206"210 It has been shown that if the ions in the solution have vibrational bands, it is possible to relate their excess density to the experimentally observed surface. 

Reciprocal electrical double layer thickness, m Compressibility index Viscosity of filtrate or liquid in a feed. Pa s Dimensionless time... 

On solid metals the situation for ion deposition or dissolution in electrode reactions is much more complicated. The models for crystal growth from the vapor phase or atomic evaporation have to be applied, being modified by ion discharge or ion formation in passing the electrical double layer at the interface. Figure 2.31 represents the main positions of atoms on the surface of a low index face of a metal with one monoatomic step. It is assumed that the edge of the step is not smooth and contains several kink sites. 

The solvent index is arranged according to single solvents, nonaqueous-aqueous mixtures and nonaqueous-nonaqueous mixtm-es. Individual solvent systems are indexed accordii to solubilities, pKsp, emf, potentiometric titrations, vapor pressure, cryoscopy, heats of solution, polarography, ligand exchange rates, electrode reactions, electrical double layer, spectroscopy, and organic electrolyte batteries. 

---